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21 total results found

Total Synthesis of Pimara-15-endiol (T. Magauer, 2020)

Total Syntheses of Natural Products Terpenoids and Terpenes

One of the most interesting biosynthetic transformation is the cyclization of terpenoids to stero...

First Total Synthesis of Bufospirostenin A (C.-C. Li, 2020)

Total Syntheses of Natural Products Steroids

Bufospirostenin A (1, Figure 1)  is a bioactive steroid from the bile and venom of the toad Bufo ...

Enantioselective Total Synthesis of Batrachotoxinin A (T. Luo, 2020)

Total Syntheses of Natural Products Alkaloids

Batrachotoxinin A (1, see Figure 1) is an alkaloid with a steroidal skeleton. The batrachtoxinins...

First Total Synthesis of Kopsinitarine E (D. Ma, 2020)

Total Syntheses of Natural Products Alkaloids

Kopsinitarine E (1) is a polycyclic alkaloid isolated from Kopsia species. In the journal Angewan...

Formal Total Synthesis of Atropurpuran (K. Tanino, 2020)

Total Syntheses of Natural Products Terpenoids and Terpenes

Atropurpuran (1) represents a complex diterpenoid featuring a pentacyclic skeleton. The research ...

First Total Synthesis of Daphnezomines A and B (C. Li, 2020)

Total Syntheses of Natural Products Alkaloids

Alkaloids from the plant genus Daphniphyllum are known for their complex structure and attracted ...

First Total Synthesis of Cryptotrione (X.S. Peng, 2020)

Total Syntheses of Natural Products Terpenoids and Terpenes

Cryptotrione (1) is a complex terpenoid isolated in 2010. Now Xiao-Shui Peng (彭小水) and coworkers ...

Total Synthesis of Ajudazol A (D. Menche, 2020)

Total Syntheses of Natural Products Polyketides

Ajudazol A (1) is a secondary metabolite of mycxobacterial origin which containing an isochromano...

First Total Synthesis of Glaucocalyxin A (Y. Jia, 2020)

Total Syntheses of Natural Products Terpenoids and Terpenes

Using a radical cyclization strategy at the very beginning of their synthesis, the Yanxing Jia (贾...

Total Synthesis of Cinnamodial and Dimerization to Capsicodendrin (S. Han, 2020)

Total Syntheses of Natural Products Terpenoids and Terpenes

The terpenoid capsicodendrin (1, Figure 1) is a dimer of cinnamodial (2) which was already isolat...

First Asymmetric Total Synthesis of Waihoensene (Z. Yang, 2020)

Total Syntheses of Natural Products Terpenoids and Terpenes

Although isolated already in 1997, the complex diterpene waihoensene was firstly synthesized twen...

Total Synthesis of Trihydroxytremulenone, Concenolide C and E by Pd-Cyclization (B. Trost, 2020)

Total Syntheses of Natural Products Terpenoids and Terpenes

Complex terpenoids like 10,11,12-trihydroxy tremulenone (1), cocenolide C (2) and E (3, Figure 1)...

Total Synthesis of racemic Phyllantidine by Ring Expansion (J. L. Wood, 2020)

Total Syntheses of Natural Products Alkaloids

Phyllantidine (1) is member of the Securinega alkaloids family named after their first isolation ...

Total Synthesis of Olivil and related Lignans (S. Hanessian, 2020)

Total Syntheses of Natural Products Lignans

Despite reported for the first time over 200 years ago, the lignan olivil (1, see Figure 1) never...

First Total Synthesis of Scabrolide A (B. M. Stoltz, 2020)

Total Syntheses of Natural Products Terpenoids and Terpenes

In 2002 Sheu et al. isolated scabrolide A (1) and other natural products from Taiwanese soft cora...

Total Synthesis of Bactobolin A (J. Švenda, 2020)

Total Syntheses of Natural Products Polyketides

Bactobolin A (1) is a complex polyketide firstly isolated in 1979 by S. Kondo et al. from bacteri...

Total Synthesis of Thebainone A (P. Metz, 2020)

Total Syntheses of Natural Products Alkaloids

Despite several total syntheses of opiates since the 50s, the construction of these complex alkal...

Bioinspired Total Synthesis of Brevianamide (A. Lawrence, 2020)

Total Syntheses of Natural Products Alkaloids

Although already isolated by Birch et al. in 1969, it took 50 years for the first total synthesis...

First Total Synthesis of Canataxpropellane (T. Gaich, 2020)

Total Syntheses of Natural Products Terpenoids and Terpenes

In their publication in Science (T. Gaich et al. Science, 2020, 367, 676) the research group of T...

Total Synthesis of Talatisamine (M. Inoue, 2020)

Total Syntheses of Natural Products Alkaloids

Talatisamine (1, see Figure 1) is a highly oxidized hexacyclic alkaloid. Isolated already almost ...